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Given :
Molar mass $N =14\,g\,mol ^{-1} ; O =16\,g\,mol ^{-1} ; C =12\,g\,mol ^{-1} ; H =1\,g\,mol ^{-1}$;
$\mathrm{Zn}\left|\mathrm{Zn}^{2+}(\mathrm{aq}),(1 \mathrm{M}) \| \mathrm{Fe}^{3+}(\mathrm{aq}), \mathrm{Fe}^{2+}(\mathrm{aq})\right| \mathrm{Pt}(\mathrm{s})$
The fraction of total iron present as $\mathrm{Fe}^{3+}$ ion at the cell potential of $1.500\, \mathrm{~V}$ is $\mathrm{X} \times 10^{-2}$. The value of $x$ is $.....$ (Nearest integer).
$\left(\right.$ Given $\left.E_{\mathrm{Fe}^{3+} / \mathrm{Fe}^{2+}}^{0}=0.77\, \mathrm{~V}, \mathrm{E}_{\mathrm{Zn}^{2+} / \mathrm{Zn}}^{0}=-0.76 \,\mathrm{~V}\right)$
$C _{2} H _{6} \rightarrow C _{2} H _{4}+ H _{2}$
the reaction enthalpy $\Delta_{ r } H =...........{ kJ\, mol ^{-1}}$.
(Round off to the Nearest Integer).
[Given : Bond enthalpies in $kJ$ $mol$ $^{-1}:C-C : 347, C = C : 611 ; C - H : 414, H - H : 436]$