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$(A)$ The decreasing order of atomic radii of group $13$ elements is $\mathrm{Tl}>\mathrm{In}>\mathrm{Ga}>\mathrm{Al}>\mathrm{B}$.
$(B)$ Down the group $13$ electronegativity decreases from top to bottom.
$(C)$ $\mathrm{Al}$ dissolves in dil. $\mathrm{HCl}$ and liberate $\mathrm{H}_2$ but conc. $\mathrm{HNO}_3$ renders Al passive by forming a protective oxide layer on the surface.
$(D)$ All elements of group 13 exhibits highly stable +1 oxidation state.
$(E)$ Hybridisation of $\mathrm{Al}$ in $\left[\mathrm{Al}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$ ion is $\mathrm{sp}^3 \mathrm{~d}^2$.
Choose the correct answer from the options given below:
| Column $I$ | Column $II$ |
| $(A)$ $CH_3COONa$ | $(i)$ Almost neutral, $pH > 7$ or $< 7$ |
| $(B)$ $NH_4Cl$ | $(ii)$ Acidic, $pH < 7$ |
| $(C)$ $NaNO_3$ | $(iii)$ Alkaline, $pH > 7$ |
| $(D)$ $CH_3COONH_4$ | $(iv)$ Neutral, $pH = 7$ |
Statement $I$: Aniline reacts with con. $\mathrm{H}_2 \mathrm{SO}_4$ followed by heating at $453-473 \mathrm{~K}$ gives $\mathrm{p}$ aminobenzene sulphonic acid, which gives blood red colour in the 'Lassaigne's test'.
Statement $II$: In Friedel - Craft's alkylation and acylation reactions, aniline forms salt with the $\mathrm{AlCl}_3$ catalyst. Due to this, nitrogen of aniline aquires a positive charge and acts as deactivating group.
In the light of the above statements, choose the correct answer from the options given below :