- A$2 \times 10^{-5}$
- B$5 \times 10^{10}$
- C$2 \times 10^{-9}$
- ✓$2 \times 10^{9}$
$\therefore \mathrm{K}_{\mathrm{N}}=\frac{1}{\mathrm{K}_{\mathrm{h}}}=\frac{1}{\left(1 / 2 \times 10^{-9}\right)}=2 \times 10^{9}$
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$\mathrm{A}+\mathrm{B} \underset{\text { Step } 3}{\text { Step } 1} \mathrm{C} \xrightarrow{\text { Step } 2} \mathrm{P}$
Some details of the above reaction are listed below.
| Step |
Rate constant $\left(\sec ^{-1}\right)$ |
Activation energy $\left(\mathrm{kJ} \mathrm{mol}^{-1}\right)$ |
| $1$ | ${k}_1$ | $300$ |
| $2$ | ${k}_2$ | $200$ |
| $3$ | ${k}_3$ | $\mathrm{Ea}_3$ |
If the overall rate constant of the above transformation (k) is given as $\mathrm{k}=\frac{\mathrm{k}_1 \mathrm{k}_2}{\mathrm{k}_3}$ and the overall activation energy $\left(E_2\right)$ is $400 \mathrm{~kJ} \mathrm{~mol}^{-1}$, then the value of $\mathrm{Ea}_3$ is $\qquad$ $\mathrm{kJ} \mathrm{mol}^{-1}$ (nearest integer)
Assume Planck's constant $( h )=6.4 \times 10^{-34}\,Js$ Speed of light $( c )=3.0 \times 10^8\,m / s$ and Avogadro's constant $\left( N _{ A }\right)=6 \times 10^{23} / mol$