MCQ
Acetic acid reacts with $PC{l_5}$to form
- ✓$C{H_3}COCl$
- B$CHC{l_2}COOH$
- C$C{H_2}ClCOOH$
- D$C{H_3}COOCl$
$\mathop {C{H_3}COOH}\limits_{Aceticacid} + \mathop {PC{l_5}}\limits_{\begin{subarray}{l}
Phosphorus \\
pentachloride
\end{subarray}} \to \mathop {C{H_3}COCl}\limits_{\begin{subarray}{l}
Acetyl \\
Chtoride
\end{subarray} } + \mathop {HCl}\limits_{\begin{subarray}{l}
Hydro - Chtortic \\
acid
\end{subarray}} +\mathop {POC{l_3}}\limits_{\begin{subarray}{l}
Phosphoryl \\
chtoride
\end{subarray} }$
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$\begin{array}{|l|l|l|} \hline {P_{{A_0}}}(atm) & 0.1 & 0.025 \\ \hline {t_{1/2}}(\sec\,\,) & 100 & 50 \\ \hline \end{array}$
The correct statement about order of reaction is