MCQ
Acidified $KMn{O_4}$ is decolourzed by
- ✓$B{r_2}$
- B${O_3}$
- C$HCl$
- D$HBr$
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The correct statement for product $B$ is. It is
$Ag(s)\,\,|\,\,A{g_2}{C_2}{O_4}(s)\,\,|\,\,{C_2}O_4^{2 - }(0.02\,M)\,\,||\,\,A{g^ + }(0.5\,M)\,\,|\,\,Ag(s)$
$EMF$ of cell is $0.264\ V$ at $25\,^oC$ . $K_{sp}$ of $Ag_2C_2O_4(s)$ is
$\left[ {Given = \frac{{2.303 \times 8.314 \times 298}}{{96500}} = \frac{{2.303RT}}{F} = 0.06,\,\log 2 = 0.3} \right]$
${C_6}{H_5}N{H_2}\mathop {\xrightarrow{{NaN{O_2}/HCl}}}\limits_{0 - 5\,^o C} X\mathop {\xrightarrow{{HN{O_2}}}}\limits_{C{H_2}O} Y + {N_2} + HCl$
$X$ and $Y$ are respectively
${N_2} + {O_2}$ $\rightleftharpoons$ $2NO - 43,200\,kcal$