Question
Among the elements B, Al, C and Si:
  1. Which has the highest first ionization enthalpy?
  2. Which has the most negative electron gain enthalpy?
  3. Which has the largest atomic radius?
Give reasons.

Answer

  1. Ionization energy increases along a period but decreases going down in the group. Hence, carbon has highest first ionization enthalpy since it has the smallest size among all.
  2. Electron gain enthalpy becomes more negative along a period and less negative down a group, thus, carbon has the most negative electron gain enthalpy due to smallest size.
  3. Atomic radii decrease along a period but increase down the group, thus, Al has the largest atomic radius.

Need a full question paper?

Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.

Start Generating Free

Similar questions

State with equations what happens when borax is heated on a platinum wire loop and the resulting transparent mass is heated with CoO in Bunsen burner.
Match Cloumn I with Column II.
S. No
Cloumn I
S. No
Cloumn II
1.
88g of $CO_2$
(i)
0.25mol
2.
$6.022 \times 10^{23}$​​​​​​​ molecules of $H_2O$
(ii)
2mol
3.
5.6 litres of $O_2​​​​​​​$ at STP
(iii)
1mol
4.
96g of $O_2​​​​​​​$
(iv)
$6.022 \times 10^{23}​​​​​​​$ molecules
5.
1mol of any gas
(v)
3mol
Use Lewis symbols to show electron transfer between the following atoms to form cations and anions: Ca and O
Explain, how is the electronegativity of carbon atoms related to their state of hybridisation in an organic compound?
The compression factor (compressibility factor) for one mole of a van der Waals gas at 0°C and 100 atm pressure is found to be 0.5. Assuming that the volume of a gas molecule is negligible, calculate the van der Waals' constant a.
What is the difference between the terms ‘hydrolysis’ and ‘hydration’?
Compare the relative stability of the following species on the basis of molecular orbital theory and indicate their magnetic properties:
$\text{O}^+_2,\text{O}^-_2,\text{O}_2^{-2}$
Among the elements of second period Li to Ne, pick out element:
  1. With the highest first ionisation energy.
  2. With highest electronegativity.
  3. With largest atomic radius.
  4. That is most reactive non-metal.
  5. That is most reactive metal.
  6. With valency equal to 4.
Lifetimes of the molecules in the excited states are often measured by using pulsed radiation source of duration nearly in the nano second range. If the radiation source has the duration of 2 ns and the number of photons emitted during the pulse source is $2.5 \times 10^{15}$, calculate the energy of the source.
Describe the theory associated with the radius of an atom as it:
1. gains an electron
2. loses an electron