- A$p$-nitrophenol
- B$p$-hydroxybenzoic acid
- ✓$o$-hydroxybenzoic acid
- D$p$-toluic acid
Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.


$(p)$ $\begin{matrix}
Ph\,\,\,\,\,O\, \\
|\,\,\,\,\,\,\,\,||\,\, \\
Ph-C-C-C{{H}_{3}} \\
|\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}\,\,\,\,\,\,\,\, \\
\end{matrix}$ $(q)$ $\begin{matrix}
\,Ph\,\,\,\,\,O\, \\
\,\,|\,\,\,\,\,\,\,\,|| \\
Ph-C-C-Et \\
|\,\,\,\,\,\,\,\,\,\, \\
Et\,\,\,\,\,\,\,\,\,\, \\
\end{matrix}$
$(r)$ $\begin{matrix}
\,Ph\,\,\,\,\,O\, \\
|\,\,\,\,\,\,\,\,\,\,||\, \\
Ph-C-C-C{{H}_{3}} \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
Et\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix}$ $(s)$ $\begin{matrix}
\,\,\,Ph\,\,\,\,\,O\, \\
\,\,|\,\,\,\,\,\,\,\,|| \\
Ph-C-C-Et \\
|\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}\,\,\,\, \\
\end{matrix}$
When $(A)$ and $(B)$ reacts with $H_2SO_4$ products obtained are
| Column $-I$ (various solutions) | Column $-II$ (Their freezing point ) | ||
| $a$ | $0.1\,M\, BaCl_2$ solution | $p$ | $271\,K$ |
| $b$ | $0.1\,M\, NaCl$ solution | $q$ | $270\, K$ |
| $c$ | $0.1\,M\, K_3 [Fe(CN)_6]$ solution | $r$ | $268\, K$ |
| $d$ | $0.1\,M\, Al_2 (SO_4)_3$ solution | $s$ | $269\, K$ |
Given : Freezing point of $0.1\,M$ sucrose solution $= 272\,K$ and $F.pt.$ of water $= 273\,K$
Which of the following option show correct matches ? (assume, molarity=molality)