$ -\mathrm{OCH}_3,-\mathrm{NO}_2,-\mathrm{CN},-\mathrm{CH}_3-\mathrm{NHCOCH}_3, $
$ -\mathrm{COR},-\mathrm{OH},-\mathrm{COOH},-\mathrm{Cl}$
- A$3$
- B$2$
- ✓$4$
- D$1$
$ -\mathrm{OCH}_3,-\mathrm{NO}_2,-\mathrm{CN},-\mathrm{CH}_3-\mathrm{NHCOCH}_3, $
$ -\mathrm{COR},-\mathrm{OH},-\mathrm{COOH},-\mathrm{Cl}$
are meta directing.
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$2 \mathrm{Fe}_{(\mathrm{s})}+\frac{3}{2} \mathrm{O}_{2(\mathrm{~g})} \rightarrow \mathrm{Fe}_2 \mathrm{O}_{3(\mathrm{~s})}, \Delta \mathrm{H}^{\mathrm{o}}=-822 \mathrm{~kJ} / \mathrm{mol}$
$\mathrm{C}_{(\mathrm{s})}+\frac{1}{2} \mathrm{O}_{2(\mathrm{~g})} \rightarrow \mathrm{CO}_{(\mathrm{g})}, \Delta \mathrm{H}^{\mathrm{o}}=-110 \mathrm{~kJ} / \mathrm{mol}$
Then enthalpy change for following reaction
$3\mathrm{C}_{(\mathrm{s})}+\mathrm{Fe}_2 \mathrm{O}_{3(\mathrm{~s})} \rightarrow 2 \mathrm{Fe}_{(\mathrm{s})}+3 \mathrm{CO}_{(\mathrm{g})}$