MCQ
An aqueous solution of potash alum gives
- ATwo types of ions
- BOnly one type of ion
- CFour types of ions
- ✓Three types of ions
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$2MnO_4^ - + 5{C_2}O_4^ - + 16{H^ + } \to 2M{n^{ + + }} + 10C{O_2} + 8{H_2}O$
Here $20\, mL$ of $0.1\, M\, KMnO_4$ is equivalent to
$2 A + B \longrightarrow C + D$
| Experiment | $[ A ] / molL ^{-1}$ | $[ B ] / molL ^{-1}$ | Initial $rate/molL$ $^{-1}$ $\min ^{-1}$ |
| $I$ | $0.1$ | $0.1$ | $6.00 \times 10^{-3}$ |
| $II$ | $0.1$ | $0.2$ | $2.40 \times 10^{-2}$ |
| $III$ | $0.2$ | $0.1$ | $1.20 \times 10^{-2}$ |
| $IV$ | $X$ | $0.2$ | $7.20 \times 10^{-2}$ |
| $V$ | $0.3$ | $Y$ | $2.88 \times 10^{-1}$ |
$X$ and $Y$ in the given table are respectively :

$[Fe(CN)_6]^{4-} \rightarrow [Fe(CN)_6]^{3-} + e^{-1}\, ;$ $ E^o = -0.35\, V$
$Fe^{2+} \rightarrow Fe^{3+} + e^{-1}\ ;$ $E^o = -0.77\, V$