MCQ
Aniline on treatment with conc. $HN{O_3} + $ conc. ${H_2}S{O_4}$ mixture yields
- A$o- $and $p-$nitroanilines
- B$m-$nitroanilines
- ✓A black tarry matter
- DNo reaction

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Step$-1$ : ${\text{A + E }} \rightleftharpoons AE$ (fast)
Step$-2$ :${\text{AE + A }} \to {A_2} + E$ (slow)
Step$-3$ :${{\text{A}}_2}{\text{ + B }} \to {\text{D}}$ (fast)
what rate law best agrees with this mechanism
| Rate constant | Activation energy | |
| Step $1$ | $k_1$ | $E_{a1} = 180\ kJ/mol$ |
| Step $2$ | $k_2$ | $E_{a2} = 80\ kJ/mol$ |
| Step $3$ | $k_3$ | $E_{a3} = 50\ kJ/mol$ |
If overall rate constant, $k = {\left( {\frac{{{k_1}{k_2}}}{{{k_3}}}} \right)^{2/3}}$ ,then overall activation energy of the reaction will be .......... $ kJ/mol$