MCQ
$\begin{array}{*{20}{c}}
  {\,\,\,\,\,\,OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {C{H_3} - CH - C{H_2} - C - H} 
\end{array}$

$3HCHO+A\xrightarrow[{{40}\,^{o}}C]{N{{a}_{2}}C{{O}_{3}}}\underset{(82\%)}{\mathop{(B)}}$

Product $(B)$ of the above reaction is

  • A
    $\begin{matrix}
       \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{2}}-OH  \\
       \,\,\,\,\,\,\,|  \\
       HO-C{{H}_{2}}-C-C{{H}_{2}}OH  \\
       \,\,\,\,\,\,\,|  \\
       \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{2}}-OH  \\
    \end{matrix}$
  • B
    $\begin{matrix}
       \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,CHO  \\
       \,\,\,\,\,\,\,\,\,\,\,\,\,|  \\
       HO-C{{H}_{2}}-C-CHO  \\
       \,\,\,\,\,\,\,\,\,\,\,\,\,|  \\
       \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{2}}-OH  \\
    \end{matrix}$
  • $\begin{matrix}
       \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{2}}OH  \\
       \,\,\,\,\,\,\,|  \\
       HO-C{{H}_{2}}-C-C{{H}_{2}}OH  \\
       \,\,\,\,\,\,\,|  \\
       \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,CHO  \\
    \end{matrix}$
  • D
    $\begin{matrix}
       CHO\,\,\,\,\,\,\,\,\,  \\
       |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
       HO-C{{H}_{2}}-C-C{{H}_{2}}-C{{H}_{2}}-OH  \\
       |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
       \,\,\,\,\,C{{H}_{2}}-OH  \\
    \end{matrix}$

Answer

Correct option: C.
$\begin{matrix}
   \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{2}}OH  \\
   \,\,\,\,\,\,\,|  \\
   HO-C{{H}_{2}}-C-C{{H}_{2}}OH  \\
   \,\,\,\,\,\,\,|  \\
   \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,CHO  \\
\end{matrix}$
c
$(c)$  $(A)\, CH_3CHO$   $(B)$ $\begin{matrix}
   \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{2}}-OH  \\
   \,\,\,\,\,\,\,\,\,\,\,\,\,|  \\
   HO-C{{H}_{2}}-C-CHO  \\
   \,\,\,\,\,\,\,\,\,\,\,\,\,|  \\
   \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{2}}-OH  \\
\end{matrix} $ (By cross aldol)

Need a full question paper?

Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.

Start Generating Free

Similar questions

In which of the following reactions aromatic aldehyde is treated with acid anhydride in presence of corresponding salt of the acid to give unsaturated aromatic acid
$MnO^-_4$ is of intense pink colour, though $Mn$ is in $( + 7)$ oxidation state, it is  due to 
$R$ is 
Identify the product $C$ in the series

  $C{H_3}CN\xrightarrow{{Na/{C_2}{H_5}OH}}A\xrightarrow{{HN{O_2}}}B\xrightarrow{{{\text{copper}}}}C$

Compounds containing both amino and $-COOH$ groups are known as
Which of the following solutions does not show positive deviation?
On treatment with chlorine in presence of sunlight, toluene gives the product
Match the complexes in Column-$I$ with their properties listed in Column-$II$. Indicate your answer by darkening the appropriate bubbles of the $4 \times 4$ matrix given in the $ORS$.
Column-$I$ Column-$II$
$(A)$ $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\left(\mathrm{H}_2 \mathrm{O}\right)_2\right] \mathrm{Cl}_2$ $(p)$ geometrical isomers
$(B)$ $\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]$ $(q)$ paramagnetic
$(C)$ $\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{Cl}\right] \mathrm{Cl}$ $(r)$ diamagnetic
$(D)$ $\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_2$ $(s)$ metal ion with $+2$ oxidation state
Which of the following methods of preparation of amines will give same number of carbon atoms in the chain of amines as in the reactant?
During the denaturation of proteins, which of these structures will remain intact?