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5. Co-ordination chemistry — Chemistry STD 12 Science — Question

Gujarat BoardEnglish MediumSTD 12 ScienceChemistry5. Co-ordination chemistry1 Mark
MCQ
$[(C_6H_5)_2 Pd (SCN)_2]$ and $[(C_6H_5)_2 Pd (NCS)_2]$ are :
  • ✓
    Linkage isomers
  • B
    Co-ordination isomers
  • C
    Ionisation isomers
  • D
    Geometrical isomers
✓

Answer

Correct option: A.
Linkage isomers
a
The given complexes contain thiocyanato (NCS) as a ligand which is an ambidentate ligand and can coordinate through two donor atoms $N$ and $S$. Hence, linkage isomerism is possible.

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