MCQ
Cis-trans isomerism is exhibited by
- A$[PtCl(NH_3)_3]^+$
- B$[Pt(NH_3)_4]^{2+}$
- C$[PtCl_4]^{2-}$
- ✓$[PtCl_2(NH_3)_2]$
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$NH_2-CH_2-CH_2-NH_2 +$ $\begin{array}{*{20}{c}}
{COO{C_2}{H_5}} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{COO{C_2}{H_5}}
\end{array}$ $\xrightarrow{{Pyridne}}$ $[X]$
$[X]$ will be :
$\mathrm{Pt}(s) \mid \mathrm{H}_2(g, 1 \text { bar })\left|\mathrm{H}^{+}(a q, 1 \mathrm{M}) \| \mathrm{M}^{4+}(a q), \mathrm{M}^{2+}(a q)\right| \mathrm{Pt}(s)$
$E_{\text {cell }}=0.092 \mathrm{~V} \text { when } \frac{\left[\mathrm{M}^{2+}(a q)\right]}{\left[\mathrm{M}^{4+}(a q)\right]}=10^x$
Given : $ E_{\mathrm{M}^4 / \mathrm{M}^{2+}}^0=0.151 \mathrm{~V} ; 2.303 \frac{R T}{F}=0.059 \mathrm{~V}$
The value of $x$ is