| Column A | Column B |
| (1) High boiling point of $H _2 O$ | (a) Paramagnetic |
| (2) $B _2$ molecule | (b) Decreasing order of bond order |
| (3) HCI < HBr < HI < HF | (c) Intramolecular H -bond |
| (4) $H _2 O > H _2 S> H _2 Se >$ $H _2 Te$ | (d) Increasing order of boiling point |
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| Column A | Column B |
| (1) Neutralization energy of HCl + NaOH | (a) Heat exchange due to difference in temperature |
| (2) Formation of mixture of gases | (b) 57.32 kJ |
| (3)$\Delta G$ > 0 | (c) increase in entropy |
| (4) Heat | (d) non-spontaneous process |
| Column A | Column B |
| (1) $\Delta H _s$ | (a) R |
| (2) $C _{ p }- C _{ V }$ | (b) System + surroundings |
| (3) Law of conservation of energy | (c) $\Delta H _{ f }+\Delta H _V$ |
| (4) Universe | (d) First law of thermodynamics |
| Column A | Column B |
| (1) Wavenumber | (a) Principal quantum numbers |
| (2) Radius of Bohr shell | (b) $2 n^2$ |
| (3) Maximum number of electrons in any orbital | (c) $\frac{1}{\lambda}$ |
| (4) K, L, M, N, O | (d) $\frac{n^2}{Z} \times 0.529 Å$ |
| Column A | Column B |
| (1) Coinage metal | (a) 28 |
| (2) Elements form $M ^{+1}$ ion | (b) Cu, Ag, Au |
| (3) All metals | (c) Alkaline metals |
| (4) Number of inner transition elements | (d) group 2 |
| Column A | Column B |
| (1) Solution of $CuSO _4$ | (a) 14 |
| (2) $SnS _2$ | (b) $pH <7$ |
| (3) Relationship of $K _{ p }$ and $K _{ c }$ | (c) $K_{s p}=4 s^3$ |
| (4) $pK _{ a }+ pK _{ b }$ | (d) $K _{ p }= K _{ c }( RT )^{\Delta n}$ |
| Column A | Column B |
| (1) Bond angle 120° | (a) $s p^3-s p^3$ overlapping |
| (2) $H _2^{-}< H _2{ }^{+}< H _2$ | (b) $\left[ Ni ( CN )_4\right]^{2-}$ |
| (3) $d s p^2$ hybridisation | (c) Benzene |
| (4) C-C bond in ethane | (d) Increasing order of stability |
| Column A | Column B |
| (1) Solution of $CH _3 COONH _4$ | (a) Salt formed by weak acid and weak base |
| (2) $NH _4 Cl$ | (b) $pH =7$ |
| (3) $NH _4 OH + NH _4 Cl$ | (c) $Kh =\frac{ K _{ w }}{ K _{ b }}$ |
| (4) $\left( NH _4\right)_2 CO _3$ | (d) Basic buffer |
| Column A | Column B |
| 1. Mustard gas | (a) $180^{\circ}$ |
| 2. PAN | (b) $HC \equiv CH$ |
| 3. $H - C - C$ bond angle in ethyne | (c) Polymer of vinyl cyanide |
| 4. Dehydrohalogenation $\text { in } CH_3 CHBr_2$ | (d) War gas |
| Column A | Column B |
| (1) $Ba ( OH )_2$ | (a) $\alpha \propto \sqrt{V}$ |
| (2) For weak acid | (b) Acidity = 2 |
| (3) Ostwald dilution law | (c) $\left[ H ^{+}\right]=\sqrt{ C . K _{ a }}$ |
| (4) For dibasic acid | (d) $K _{ a _2}< K _{ a _1}$ |
| Column A | Column B |
| 1. Bayer's reagent | (a) $C _{12}$ to $C _{16}$ |
| 2. Ozonolysis of but-2-ene | (b) $CH _3- CH _2- CHO$ |
| 3. Hydroformylation of ethene | (c) Test for unsaturation |
| 4. Kerosene oil | (d) $CH _3 CHO$ |