Question
Describe a method for refining nickel.

Answer

Nickel is refined by Mond's process. In this process, nickel is heated in the presence of carbon monoxide to form nickel tetracarbonyl, which is a volatile complex.
$\text{Ni}+4\text{C}\text{O}\xrightarrow[]{\ \ \ 330-350\text{k}\ \ \ }\text{Ni}(\text{C}\text{O})_4\\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{Nickel tetracarbonyl}$
Then, the obtained nickel tetracarbonyl is decomposed by subjecting it to a higher temperature (450 - 470K) to obtain pure nickel metal.
$ \begin{matrix}\text{Ni}(\text{C}\text{O})_4& \xrightarrow[]{\ \ \ 330-350\text{k}\ \ \ }&\text{Ni}+4\text{CO} \\\text{Nickel tetracarbonyl}&&\text{Nickle}\ \ \ \ \ \ \ \ \ \ \ \ \ \end{matrix}$

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