Question
Distinguish between electrolytic and galvanic cells.

Answer

Electrolytic cell:

  1. This device is used to bring about a non-spontaneous chemical reaction by passing an electric current.
  2. It is used to bring about a chemical reaction generally for the dissociation (electrolysis) of compounds.
  3. In this cell, electrical energy is converted into chemical energy.
  4. In this cell, the cathode is negative and the anode is positive.
  5. Electrolytic cells are irreversible.
  6. Oxidation takes place at the positive electrode and reduction at the negative electrode.
  7. The electrons are supplied by the external source and enter through cathode and come out through anode.
  8. It is used for electroplating, electrorefining, etc.

Electrochemical cell (Galvanic cell or Voltaic cell):

  1. This device is used to produce electrical energy by a spontaneous chemical reaction.
  2. It is used to generate electricity.
  3. In this cell, chemical energy is converted into electrical energy.
  4. In this cell, the cathode is positive and the anode is negative.
  5. Electrochernical cells are reversible.
  6. Oxidation takes place at the negative electrode and reduction at the positive electrode.
  7. The electrons move from anode to cathode in the external circuit.
  8. It is used as a source of electric current.

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