Question
Explain heterolytic cleavage with suitable example.
✓
Answer
Heterolytic cleavage:
i. In hetcrolytic cleavage of a covalent bond, both shared electrons go to one of the two bonded atoms.
ii. This type of cleavage gives rise to two charged species, one with negative charge (anion) and the other with positive charge (cation).
iii. The negatively charged species has the more electronegative atom which has taken away the shared pair of electrons with it.
iv. Heterolytic cleavage can be represented as follows:
Where B is more electronegative than A and the movement of an electron pair is represented by a curved arrow.
v. Thus, the unsymmetrical breaking of a covalent bond between two atoms in such a way that the more electronegative atom acquires both the electrons of the shared pair. thereby fòrming charged ions is known as heterolytic fission or heterolysis.
i. In hetcrolytic cleavage of a covalent bond, both shared electrons go to one of the two bonded atoms.
ii. This type of cleavage gives rise to two charged species, one with negative charge (anion) and the other with positive charge (cation).
iii. The negatively charged species has the more electronegative atom which has taken away the shared pair of electrons with it.
iv. Heterolytic cleavage can be represented as follows:
Where B is more electronegative than A and the movement of an electron pair is represented by a curved arrow.
v. Thus, the unsymmetrical breaking of a covalent bond between two atoms in such a way that the more electronegative atom acquires both the electrons of the shared pair. thereby fòrming charged ions is known as heterolytic fission or heterolysis.
Need a full question paper?
Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.
Explore more
Similar questions
Explain catalytic selectivity with suitable examples.
The half $-$ life of ${ }^{34} Cl$ is $1.53 s$. How long does it take for $99.9 \%$ of sample of ${ }^{34} Cl$ to decay?
→What are colloids? Explain.
What do you mean by reaction mechanism? Give importance of reaction mechanism.
Complete the table:
Write condensed electronic configurations of the following elements.
$
{ }_{13} Al ,{ }_{49} In ,{ }_{14} Si ,{ }_{50} Sn ,{ }_{15} P ,{ }_{33} As
$
Differentiate between $s-$block and $p-$block elements.
→Display electron distribution around the oxygen atom in water molecule and state shape of the molecule, also write H-O-H bond angle.
Explain : electronegativity and electron gain enthalpy. Which of the two can be measured experimentally?
How is ammonia manufactured by Haber process?