Question
Explain peroxide effect.
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(i) $Ce ^{+4}$ is a strong oxidant, why?
(ii) $Eu ^{2+}$ is a strong reducing agent, why?
→(ii) $Eu ^{2+}$ is a strong reducing agent, why?
State the general physical properties of amine compounds.
Note: In the following questions a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
Reason: Concentration of ionic solution will change if DC source is used.
- Both assertion and reason are true and the reason is the correct explanation of assertion.
- Both assertion and reason are true and the reason is not the correct explanation of assertion.
- Assertion is true but the reason is false.
- Both assertion and reason are false.
- Assertion is false but reason is true.
Reason: Concentration of ionic solution will change if DC source is used.
What are metal carbonyls? Explain with examples.
Which alkyl halide from the following pairs would you expect to react more rapidly by an SN2 mechanism? Explain your answer.
$\text{CH}_3\text{CH}_2\text{CH}_2\text{CH}_2\text{Br}\ \text{or}\ \text{CH}_3\text{CH}_2\text{CH}\text{CH}_3\\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \mid\\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{Br}$
→$\text{CH}_3\text{CH}_2\text{CH}_2\text{CH}_2\text{Br}\ \text{or}\ \text{CH}_3\text{CH}_2\text{CH}\text{CH}_3\\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \mid\\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{Br}$
Complete the following equations :
(i) $CH _3- CH _2- Cl \xrightarrow{+ A } B \xrightarrow{ C } CH _3- CH _2- NH _2+ HCOOH$
(ii) $CH _3- I \xrightarrow{+ A } B \xrightarrow{ C } CH _3- NH - CH _3$
→(i) $CH _3- CH _2- Cl \xrightarrow{+ A } B \xrightarrow{ C } CH _3- CH _2- NH _2+ HCOOH$
(ii) $CH _3- I \xrightarrow{+ A } B \xrightarrow{ C } CH _3- NH - CH _3$
Explain Raoult's Law as a special case of Henry's Law
(i) How can be prepared ethane from $CH _{3^{-}}$ $I , Mg$ and dry ether?
(ii) Write the equation to prepare ethyl ethanoate from $CH _3 COOH$.
→(ii) Write the equation to prepare ethyl ethanoate from $CH _3 COOH$.
A galvanic cell has electrical potential of 1.1V. If an opposing potential of 1.1V is applied to this cell, what will happen to the cell reaction and current flowing through the cell?
Give the major products that are formed by heating the following ethers with HI.
$ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{|}\\\text{CH}_3-\text{CH}_2-\text{CH}_2-\text{O}-\text{C}-\text{CH}_2-\text{CH}_3\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{|}\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3$
→$ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{|}\\\text{CH}_3-\text{CH}_2-\text{CH}_2-\text{O}-\text{C}-\text{CH}_2-\text{CH}_3\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{|}\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3$