Question
Explain the Bohr model for the hydrogen atom.

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The effect of uncertainty principle is significant only for motion of microscopic particles and is negligible for the macroscopic particles. Justify the statement with the help of a suitable example.
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  2. What is the basis of Hess's Law?
  3. For a gaseous reaction 2A2(g) + 5B2(g) → 2A2B5(g) at 27°C, the heat change at constant pressure is found to be -50.16kJ. Calculate the value of internal energy change $(\Delta\text{U}).$

Given: R = 8.314JK-1mol-1

The ionization constant of dimethylamine is 5.4 × 10–4. Calculate its degree of ionization in its 0.02M solution. What percentage of dimethylamine is ionized if the solution is also 0.1M in NaOH?
Balance the following ionic equations.
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What do you understand by following?
  1. Dissociation constant of an acid.
  2. Buffer solution.
  3. Solubility product.
Describe the properties of covalent compounds.
Attempt any five of the following:
(a) What happens when benzene is treated with acetyl chloride in presence of $AlCl _3$ ?
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(e) Why is $CH _2= CH - CH _2- Cl$ more easily hydrolysed than $CH _3- CH _2- CH _2- Cl$ ?
(f) Which of the two trans-but-2-ene or trans-pent-2-ene is non-polar?
(g) What are benzenoids?
While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?
At 1127K and 1 atm pressure, a gaseous mixture of CO and CO2 in equilibrium with soild carbon has 90.55% CO by mass
$\text{C (S) + CO}_2\text{ (g)}\rightleftharpoons2\text{CO (g)}$
Calculate Kc for this reaction at the above temperature.