Question
Explain the cyclic structure of glucose.

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  1. Why do transition elements show variable oxidation states?
  1. Name the element showing maximum number of oxidation states among the first series of transition metals form Sc (Z=21) to Zn (Z=30).
  2. Name the element which shows only +3 oxidation state.
  1. What is lanthanoid contraction? Name an important alloy which contains some of the lanthanoid metals.
Differentiate between $1^{\circ}, 2^{\circ}$ and $3^{\circ}$ alcohols by catalytic dehydrogenation.
A mixed oxide of iron and chromium, FeOCr2O3 is fused with sodium carbonate in the presence of air to form a yellow coloured compound (A). On acidification the compound (A) forms an orange coloured compound (B), which is a strong oxidising agent.
  1. Identify the compounds (A) and (B).
  2. Write balanced chemical equation for each step.
A first order reaction takes 30 min for 50% completion, what would be time for its 90% completion.
Write two applications of electrochemical series.
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Match the property given in Column I with the element given in Column II.
 
Column I (Property)
 
Column II (Element)
(i)
Lanthanoid which shows +4 oxidation state
(a)
Pm
(ii)
Lanthanoid which can show +2 oxidation state
(b)
Ce
(iii)
Radioactive lanthanoid
(c)
Lu
(iv)
Lanthanoid which has 4felectronic configuration in +3 oxidation state
(d)
Eu
(v)
 Lanthanoid which has 4f14 electronic configuration in +3 oxidation state
(e)
Gd
 
 
(f)
Dy
Match the coordination compounds given in Column I with the central metal atoms given in Column II and assign the correct code:
 
Column I (Coordination Compound)
 
Column II (Central metal atom)
a.
Chlorophyll
1.
Rhodium
b.
Blood pigment
2.
Cobalt
c.
Wilkinson catalyst
3.
Calcium
d.
Vitamin B12
4.
Iron
 
 
5.
Magnesium
Code:
  1. A (5), B (4), C (1), D (2).
  2. A (3), B (4), C (5), D (1).
  3. A (4), B (3), C (2), D (1).
  4. A (3), B (4), C (1), D (2).
What is called a battery? Explain its characteristics and describe dry cell and mercury cell.