Question
Explain the laboratory methods for the preparation of dioxygen.

Answer

(i) By heating chlorates, nitrates and permanganates.
Potassium chlorate in the presence of manganese dioxide on heating decomposes to form potassium chloride and oxygen.
$2 KClO _3 \xrightarrow[ MnO _2]{\Delta} 2 KCl +3 O _{2( g )}$
(ii) By the thermal decomposition of metal oxides.
$\begin{aligned}
& 2 Ag _2 O _{( s )} \xrightarrow{\text { heat }} 4 Ag + O _{2( g )} \\
& 2 HgO _{( s )} \xrightarrow{\text { heat }} 2 Hg + O _{2( g )} \\
& 2 PbO _{2( s )} \xrightarrow{\text { heat }} 2 PbO _{( s )}+ O _{2( g )}
\end{aligned}$
(iii) By the thermal decomposition of hydrogen peroxide :
The thermal decomposition of hydrogen peroxide in the presence of finely divided metal and manganese dioxide used as catalyst gives oxygen.
\92 H _2 O _{2 \text { (aq) }} \xrightarrow[ MnO _2]{\text { heat }} 2 H _2 O _{( l )}+ O _{2( g )}$

Need a full question paper?

Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.

Start Generating Free

Similar questions

Write a mathematical formula for mole ratio. How long will it take to produce $2.415g$ of Ag metal from its salt solution by passing a current of $3A$? Molar mass of $Ag= 107.9\ g\ mol^{-1}$​​​​​​​.
Write a chemical reaction to convert glucose into glucose cyanohydrin.
Draw the diagram for the determination of standard electrode potential with SHE.
Calculate the amount of $CaCl_2 ($van't Hoff factor, $i = 2.47)$ dissolved in $2.5 L$ solution so that its osmotic pressure at $300K$ is $0.75$ atmosphere.
$[$Given: Molar mass of $CaCl_2$ is $111 \ g \ mol^{-1} , R= 0.082 \ L \ atm \ K^{-1} \ mol^{-1}.]$
What is metamerism? Write the structure and $\text{IUPAC}$ name of 'methyl$-$n$-$propyl ether.
What is the action of hot $\text{HI}$ on it?
The decomposition of $N _2 O _{5( g )}$ at $320 K$ according to the following equation follows first order reaction:
$N _2 O _{5( g )} \longrightarrow 2 NO _{2( g )}+\frac{1}{2} O _{2( g )}$
The initial concentration of $N _2 O _{5( g )}$ is $1.24 \times 10^{-2} \ mol.L^{-1}$ and after $60$ minutes, $0.20 \times 10^{-2} mol ^{-1} L ^{-1}$.
Calculate the rate constant of the reaction at $320 K$.
Boiling point of water at $750 mm$ of $Hg$ is $99.63^{\circ} C$. How much sucrose must be added to 500 $g$ of water so that it boils at $100^{\circ} C ?\left( K _{ b }=0.52 K kg mol ^{-1}\right)$
Explain optical isomerism in 2-chlorobutane.
Explain Cross Cannizzaro reaction. Draw structure of Zwitter ion of sulfanilic acid.
Write one example of nanomaterial used in the following.
ancient glass painting