Question
Explain the limitations of valence bound theory.

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A colourless substance $'A\ ' (C_6H_7N)$ is sparingly soluble in water and gives a water soluble compound $'B\ '$ on treating with mineral acid. On reacting with $CHCl_3$ and alcoholic potash $'A\ '$ produces an obnoxious smell due to the formation of compound $'C\ '$. Reaction of $'A\ '$ with benzenesulphonyl chloride gives compound $'D\ '$ which is soluble in alkali. With $NaNO_2$ and $\text{HCl,} 'A\ '$ forms compound $'E\ '$ which reacts with phenol in alkaline medium to give an orange dye $'F\ '.$ Identify compounds $'A\ '$ to $'F\ '.$
Expian the basic properties of amines.
Draw the structures of optical isomers of:
i. $\left[ Cr \left( C _2 O _4\right)_3\right]^{3-}$
ii. $\left[ PtCl _2( en )_2\right]^{2+}$
iii. $\left[ Cr \left( NH _3\right)_2 Cl _2( en )\right]^{+}$
Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?
Match the terms given in Column $I$ with the units given in Column $II.$
 
Column $I$
 
Column $II$
$i.$ $∧_m$ $a.$ $\ce{S cm^{-1}}$
$ii.$ $\ce{E}_{\ce{Cell}}$ $b.$ $m^-$
$iii.$ $K$ $c.$ $\ce{S cm^2 mol^{-1}}$
$iv.$ $G^*$ $d.$ $V$
What is packing efficiency? Determine the packing efficiency of hcp and ccp structure.
Match the solutions given in Column $I$ and the colours given in Column $II.$
 
Column $I ($Aqueous solution of salt$)$
 
Column $II($Colour$)$
$(i)$ $\ce{FeSO_4.7H_2O}$ $(a)$
Green
$(ii)$ $\ce{NiCl_2.4H_2O}$ $(b)$
Light pink
$(iii)$ $\ce{MnCl_2.4H_2O}$ $(c)$
Blue
$(iv)$ $\ce{CoCl_2.6H_2O}$ $(d)$
Pale green
$(v)$ $\ce{Cu_2Cl_2}$ $(e)$
Pink
 
 
$(f)$
Colourless
(a) Give reasons for the following:
(i) Sulphur in vapour state shows paramagnetic behaviour.
(ii) $N - N$ bond is weaker than $P - P$ bond.
(iii) Ozone is thermodynamically less stable than oxygen.
(b) Write the name of gas released when Cu is added to
(i) dilute $HNO _3$ and (ii) conc. $HNO _3$.
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  2. Name the main disease caused due to lack of the vitamin and its source in each of the following: $A, B_6$ and $E.$
Complete the following reactions :
(i) $C _6 H _5 NH _2+ CHCl _3+$ alc. $KOH \longrightarrow$
(ii) $C _6 H _5 N_2 Cl + H _3 PO _2+ H _2 O \longrightarrow$
(iii) $C _6 H _5 NH _2+ H _2 SO _4$ (conc.) ⟶
(iv) $C _6 H _5 N_2 Cl + C _2 H _5 OH \longrightarrow$
(v) $C _6 H _5 NH _2+ Br _2(a q) \longrightarrow$