Question
Explain the oxidation of primary, secondary and tertiary alcohols.

Answer

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  1. Account for the following:
    1. Mn shows the highest oxidation state of +7 with oxygen but with fluorine it shows the highest oxidation state of +4.
    2. Cr2+ is a strong reducing agent.
    3. Cu2+ salts are coloured while Zn2+ salts are white.
  2. Complete the following equations:
    1. $2\text{MnO}_{2} + 4\text{KOH} + \text{O}_{2} \xrightarrow{\Delta}$
    2. $\text{Cr}_{2}\text{O}^{2-}_{7}+ 14\text{H}^{+} + 6\text{I}^{-}\rightarrow.$
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  3. Nucleotides.
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  1. Following are the transition metal ions of 3d series:

Ti4+, V2+, Mn3+, Cr3+

(Atomic numbers : Ti = 22, V = 23, Mn = 25, Cr = 24)

Answer the following:

  1. Which ion is most stable in an aqueous solution and why?
  2. Which ion is a strong oxidising agent and why?
  3. Which ion is colourless and why?
  1. Complete the following equations:
  1. $2\text{ }\text{MnO}_4^-+16\text{ }\text{H}^++5\text{ }\text{S}^{2-}\xrightarrow{\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }}$
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The decomposition of a hydrocarbon follows the equation.

$\text{k}=(4.5\times10^{11}\text{s}^{-1})\text{e}^{-28000}\text{ K/T}$

Calculate Ea.