- A$SO_2$ and $SO_3$
- B$SO_2$ only
- ✓$SO_3$ only
- D$H_2S$ only
${S^{2 - }}\, + \,{[Fe{(CN)_5}NO]^{2 - }}\, \to \,\mathop {{{[Fe{{(CN)}_5}NOS]}^{4 - }}}\limits_{violet} $
Thus $S^{2-}$ and $SO_3^{2-}$ can be distinguished by using both the given reagents.
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$2 Fe _{( s )}+ O _{2( g )}+4 H _{( aq )}^{+} \rightarrow 2 Fe _{( aq )}^{2^{+}}+2 H _2 O ( l ) \quad E ^{\circ}=1.67 V$, At $\left[ Fe ^{2+}\right]=10^{-3} M , P \left( O _2\right)=0.1$ atm and $pH =3$, the cell potential at $25^{\circ} C$ is
$(I)$ $\left[ {{{\left( {P{h_3}P} \right)}_2}PdC{l_2}PdC{l_2}} \right]$
$(II)$ $\left[ {NiBrCl\left( {en} \right)} \right]$
$(III)$ $N{a_4}\left[ {Fe{{\left( {CN} \right)}_5}NOS} \right]$
$(IV)$ $Cr{(CO)_3}{\left( {NO} \right)_2}$
$(I)$ - $(II)$ - $(III)$ - $(IV)$
image$\mathop {\xrightarrow{{NaN{O_2}}}}\limits_{HCl} A\,\,\xrightarrow{{CuCN}}B\,\,\mathop {\xrightarrow{{{H_2}}}}\limits_{Ni} C\,\,\xrightarrow{{HN{O_2}}}D$