MCQ
For which order reaction a straight line is obtained along with $x\,-$ axis by plotting a graph between half life $({t_{1/2}})$ and initial concentration $ 'a'$
- A$2$
- ✓$1$
- C$3$
- D$0$
The graph to be straight line $t_{\frac{1}{2}}$ should be independent of $a$ That is $1-n=0,$ hence $n=1$
It is a first order reaction.
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| Exp. | $[A]\,(mol\,L^{-1})$ | $[B]\,(mol\,L^{-1})$ | Initial rate $(mol\,L^{-1}\,s^{-1})$ |
| $1.$ | $2.5\times 10^{-4}$ | $3\times 10^{-5}$ | $5\times 10^{-4}$ |
| $2.$ | $5\times 10^{-4}$ | $6\times 10^{-5}$ | $4\times 10^{-3}$ |
| $3.$ | $1\times 10^{-3}$ | $6\times 10^{-5}$ | $1.6\times 10^{-2}$ |
Product $(B)$ is




${N_2}(g)\, + 3{H_2}(g)\, \rightleftharpoons \,2N{H_3}(g)$
The equilibrium constant of the above reaction is $K_3$. If pure ammonia is left to dissociate, the partial pressure of ammonia at equilibrium is given by (Assume that $P_{NH_3}<\,< P_{total}$ at equilibrium)