- AZinc with cold and dilute $HNO_3$
- B$Zn$ with conc. $HNO_3$
- ✓Copper with cold and dilute $HNO_3$
- DHeating $NH_4NO_3$
$Cu +\text { cold } HNO _3 \rightarrow 3 Cu \left( NO _3\right)_2+4 H _2 O +2 NO$
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Reason : $Zn$ is deposited at anode, and $Cu$ is deposited at cathode.


$Q (47 \%)$ and $R (2 \%)$. The major product(s) of the following reaction sequence is (are)
$\begin{array}{l}\begin{array}{ll}\text { 1) } Ac _2 O \text {, pyridine } \quad \text { 1) } Sn / HCl \end{array} \\ R \xrightarrow{2) Br _2, CH _3 CO _2 H } S \quad \xrightarrow{2) Br _2 / H _2 O \text { (excess) }} \text { major product(s) } \\ \text { 3) } H _3 O ^{+} \quad \text {3) } NaNO _2, HCl / 273-278 K \\ \text { 4) } NaNO _2, HCl / 273-278 K \quad \text { 4) } H _3 PO _2 \\ \text { 5) } EtOH , \Delta \\\end{array}$