4. Chemical bonding and molecular structure — Chemistry STD 11 Science — Question

$L(1s^2, 2s^2 2p^4); Q(1s^2, 2s^2 2p^6, 3s^2 3p^5)$
$P(1s^2, 2s^2 2p^6, 3s^1); R(1s^2, 2s^2 2p^6, 3s^2)$

The formulae of ionic compounds that can be formed between these elements are

(image)

The transition temperature for $\alpha$ to $\beta$ phase change is $600 \mathrm{~K}$ and $C_{p, \beta}-C_{p, \alpha}=1 \mathrm{~J} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}$. Assume $\left(C_{p, \beta}-C_{p, \alpha}\right)$ is independent of temperature in the range of 200 to $700 \mathrm{~K} . \mathrm{C}_{p, \alpha}$ and $C_{p, \beta}$ are heat capacities of $\alpha$ and $\beta$ phases, respectively.

($1$)The value of entropy change, $\mathrm{S}_\beta-\mathrm{S}_\alpha$ (in $\mathrm{J} \mathrm{mol}^{-1} \mathrm{~K}^{-1}$ ), at $300 \mathrm{~K}$ is. . . . . . .

[Use : $\ln 2=0.69$  Given : $S_\beta-S_\alpha=0$ at $\left.0 \mathrm{~K}\right]$

($2$) The value of enthalpy change, $\mathrm{H}_\beta-\mathrm{H}_\alpha$ (in $J$ mol ${ }^{-1}$ ), at $300 \mathrm{~K}$ is

Give the answer quetion ($1$) and ($2$)

Statement $I :$ A mixture of chloroform and aniline can be separated by simple distillation.

Statement $II :$ When separating aniline from a mixture of aniline and water by steam distillation aniline boils below its boiling point. In the light of the above statements, choose the most appropriate answer from the options given below.