- ✓$sp$
- B$sp^2$
- C$sp^3$
- D$sp^3d$
Number of Hybridization $=$ Valence electron $+$ monovalent $+$ (negative charge $)-($ positive charge $) / 2$
If we look at the iodine atoms there are seven valence electrons in its outer shell and two monovalent atoms are also present. Further, during the combination of Iodine with the two other lodine atoms, the central atom gains a negative charge whose value will be taken as 1 .
If we place or substitute the values according to the formula, we get
$7+1+2 / 2$
$=10 / 2$
$=5$
Therefore the hybridisation number is equal to $5$. Now we can say that hybridisation is $sp ^3 d$.
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Reason : In the complex, the coordination number of $Fe$ is $6$.
$Cu^+ /Cu = + 0.52\, V$,
$Fe^{3+} /Fe^{2+} = +0.7 7\, V$,
$\frac{1}{2}{I_2}\left( s \right)/{I^ - }\, = + 0.54\,V,$
$Ag^+ /Ag = + 0.88\,V$.
Based on the above potentials, strongest oxidizing agent will be
$\Delta_f G^0[\mathrm{C}(\text { graphite })]=0 \mathrm{kJmol}^{-1}$
$\Delta_f G^0[\mathrm{C}(\text { diamond })]=2.9 \mathrm{kJmol}^{-1}$
The standard state means that the pressure should be $1$ bar, and substance should be pure at a given temperature. The conversion of graphite [C(graphite)] to diamond [C(diamond)] reduces its volume by $2 \times 10^{-6} \mathrm{~m}^3 \mathrm{~mol}^{-1}$. If $\mathrm{C}$ (graphite) is converted to $\mathrm{C}$ (diamond) isothermally at $\mathrm{T}=298 \mathrm{~K}$, the pressure at which $C$ (graphite) is in equilibrium with C(diamond), is
[Useful information: $1 \mathrm{~J}=1 \mathrm{~kg} \mathrm{~m}^2 \mathrm{~s}^{-2} ; 1 \mathrm{~Pa}=1 \mathrm{~kg} \mathrm{~m}^{-1} \mathrm{~s}^{-2} ; 1 \mathrm{bar}=10^5 \mathrm{~Pa}$ ]