- A$2$
- B$10$
- C$11$
- ✓$12$
$[{H^ + }] = {10^{ - 12}},\,\,pH = - \log [{H^ + }] = 12$
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Assertion $(A)$ $:$ When Cu $(II)$ and sulphide ions are mixed, they react together extremely quickly to give a solid.
Reason $(R)$ $:$ The equilibrium constant of $Cu ^{2+}( aq )+ S ^{2-}( aq ) \rightleftharpoons \operatorname{CuS}( s )$ is high because the solubility product is low.
$\left[\right.$ Use $: \mathrm{H}^{+}(\mathrm{aq})+\mathrm{OH}^{-}(\mathrm{aq}) \rightarrow \mathrm{H}_{2} \mathrm{O}: \Delta_{\mathrm{\gamma}} \mathrm{H}=-57.1\, \mathrm{k} \mathrm{J} \,\mathrm{mol}^{-1}$
Specific heat of $\mathrm{H}_{2} \mathrm{O}=4.18 \mathrm{Jk}^{-} \mathrm{g}^{-}$
density of $\mathrm{H}_{2} \mathrm{O}=1.0\, \mathrm{~g} \mathrm{~cm}^{-3}$
Assume no change in volume of solution on mixing.]