- A$S _{2} O _{7}^{2-}$
- B$S _{2} O _{8}^{2-}$
- C$SO _{3}^{2-}$
- ✓$SO _{4}^{2-}$
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$\begin{array}{*{20}{c}}
{\,\,\,\,\,OH\,\,\,\,\,\,\,OH} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{C{H_3} - CH - C - C{H_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}}
\end{array}\xrightarrow{{HI{O_4}}}(a) + (b)$
$(a)$ and $(b)$ respectively be :
${{H}_{2}}+C{{l}_{2}}\xrightarrow{\text{Sunlight}}2HCl$
| Run | $[A]/mol\,L^{-1}$ | $[B]/mol\,L^{-1}$ | Initial rate of formation of $D/mol\,L^{-1}\,min^{-1}$ |
| $I.$ | $0.1$ | $0.1$ | $6.0 \times 10^{-3}$ |
| $II.$ | $0.3$ | $0.2$ | $7.2 \times 10^{-2}$ |
| $III.$ | $0.3$ | $0.4$ | $2.88 \times 10^{-1}$ |
| $IV.$ | $0.4$ | $0.1$ | $2.40 \times 10^{-2}$ |
Based on the above data which one of the following is correct?
Product $(B)$ of above reaction is
$2 X + Y \xrightarrow{i} P$
the rate of reaction is $\frac{ d [ P ]}{ dt }=k[ X ]$. Two moles of $X$ are mixed with one mole of $Y$ to make $1.0 L$ of solution. At $50 s , 0.5$ mole of $Y$ is left in the reaction mixture. The correct statement(s) about the reaction is(are)
(Use: $\ln 2=0.693$ )
$(A)$ The rate constant, $k$, of the reaction is $13.86 \times 10^{-4} s ^{-1}$.
$(B)$ Half-life of $X$ is $50 s$.
$(C)$ At $50 s ,-\frac{ d [ X ]}{ dt }=13.86 \times 10^{-3} mol L ^{-1} s ^{-1}$.
$(D)$ At $100 s ,-\frac{ d [ Y ]}{ dt }=3.46 \times 10^{-3} mol L ^{-1} s ^{-1}$.
