MCQ
In neutral or alkaline solution, $MnO _{4}^{-}$oxidises thiosulphate to.
  • A
    $S _{2} O _{7}^{2-}$
  • B
    $S _{2} O _{8}^{2-}$
  • C
    $SO _{3}^{2-}$
  • $SO _{4}^{2-}$

Answer

Correct option: D.
$SO _{4}^{2-}$
d
$8 MnO _{4}^{-}+3 S _{2} O _{3}^{2-}+ H _{2} O \frac{\text { neutral or }}{\text { alk. solution }} 88 MnO _{2}+6 SO _{4}^{2-}+2 OH ^{-}$

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$\begin{array}{*{20}{c}}
  {\,\,\,\,\,OH\,\,\,\,\,\,\,OH} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\ 
  {C{H_3} - CH - C - C{H_3}} \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\ 
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$\begin{matrix}
   O\,\,\,  \\
   ||\,\,\,  \\
   C{{H}_{3}}-C-C{{H}_{2}}-  \\
\end{matrix}\begin{matrix}
   O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   ||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
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