MCQ
In which alkyl halide, $S{N^2}$ mechanism is favoured maximum
- ✓$C{H_3}Cl$
- B$C{H_3}C{H_2}Cl$
- C${(C{H_3})_2}CHCl$
- D${(C{H_3})_3}C - Cl$
${S_{{N^1}}}$ Substitution nucleophilic unimolecular order of different alkyl halides , ${3^o} > {2^o} > {1^o}$.
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${\left( {C{H_3}} \right)_2}CHN = NCH{\left( {C{H_3}} \right)_2}\left( g \right)\xrightarrow[{{{\text{N}}_2}{\text{(g) + }}{{\text{C}}_6}{{\text{H}}_{14}}{\text{(g)}}}]{{250 - 290{}\,^oC}}$
It is found to be a first order reaction. If initial pressure is $P_o$ and pressure of the mixture at time $t$ is $(P_t)$ then rate constant $K$ would be
$C{H_3}C{H_2}C{H_2}Br\xrightarrow{{KOH(alc)}}(A)\xrightarrow{{HBr}}(B)\xrightarrow{{KOH\,(aq.)}}(C),$