- A$4f$
- B$4d$
- C$3p$
- ✓$5s$
According to aufbau principle, the correct order of energy of $4 p$ and $5 s$-orbitals is $4 p \,<\,5 s$
Aufbau principle:
In the ground state of the atoms, the orbitals are filled with electrons in order of increasing energy.
The $4 p$ sub-energy level is at a lower energy than the $5$ sub-energy level
For $4 p , n =4$ and $1=1$. Hence, $( n +1)=4+1=5$
For $5 s , n =5$ and $1=0$. Hence, $( n +1)=5+0=5$
As the value of $( n +1)$ for $4 p$ orbital is same as that of $5 s$ orbital, $4 p$ orbital is filled before $5$ orbital as $4 p$ orbital has lower value of $n$ than $5 s$ orbital.
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$(II)$ (figure)
$(III)\, CH_3-N=CH_2$
$(IV)\, C_2H_5-CH=N-OH$

$A \to B$ ${K_1} = {10^{15}}{e^{ - 25000/8.314\,T}}$
$C \to D$ ${K_2} = {10^{14}}{e^{ - 15000/8.314\,T}}$