MCQ
Lassaigne's test is used for detection of :
- ANitrogen and Sulphur only
- BNitrogen, Sulphur and Phosphorous Only
- CPhosphorous and halogens only
- ✓Nitrogen, Sulphur, phosphorous and halogens
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Statement $II :$ there is no change when undergoing boiling
Statement $III :$ reverse of $I$ and $II$
Statement $IV :$ dimer formation in freezing and boiling state
$\frac{1}{2}C{l_2}(g)\xrightarrow{{\frac{1}{2}{\Delta _{diss}}{H^\Theta }}}Cl(g)\xrightarrow{{{\Delta _{eg}}{H^\Theta }}}$ $C{l^ - }(g)\xrightarrow{{{\Delta _{Hyd}}{H^\Theta }}}C{l^ - }(aq)$
(using the data,
${{\Delta _{diss}}H_{C{l_2}}^\Theta } = 240\,kJ\,mol^{-1}, {{\Delta _{eg}}H_{C{l}}^\Theta }= -349 \,kJ\,mol^{-1},$${{\Delta _{Hyd}}H_{C{l}}^\Theta }= -381 \,kJ\,mol^{-1}$ ) will be ............. $\mathrm{kJ\,mol}^{-1}$