MCQ
Lewis acid are those substances
- ✓Which accept electron pair
- BWhich provide ${H^ + }$ion in the solution
- CWhich give electron pair
- DWhich accept $O{H^ - }$ion
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$(i) \,\,\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - C - CH - C{H_3}} \\
{\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,OH}
\end{array}\,\xrightarrow{{{H^ + }/heat}}\,\,\mathop A\limits_{[Major\,product]} \, + \,\mathop B\limits_{[Minor\,product]} $
$(ii)\,\, A\xrightarrow[{in\,\,absence\,\,\,of\,peroxide}]{{HBr,\,dark}}\,\,\mathop C\limits_{[Major\,product]} \, + \,\mathop D\limits_{[Minor\,product]} $
the major products $(A)$ and $(C)$ are respectively
$\operatorname{cis}-\left[\mathrm{Cr}(\mathrm{ox})_2 \mathrm{Cl}_2\right]^{3-},\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}$
$\operatorname{cis}-\left[\mathrm{Pt}(\mathrm{en})_2 \mathrm{Cl}_2\right]^{2+}, \text { cis }-\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]^{+}$
$\text {trans }-\left[\mathrm{Pt}(\mathrm{en})_2 \mathrm{Cl}_2\right]^{2+}, \text { trans }-\left[\mathrm{Cr}(\mathrm{ox})_2 \mathrm{Cl}_2\right]^{3-}$
(Round off to the Nearest Integer).