Question
Lithium floats an water while sodium floats and catches fire when put in water.

Answer

  • When lithium and sodium react with water, hydrogen gas is released. Due to these hydrogen gas bubbles, lithium and sodium floats on water.
    eg. $2Na + 2H_2O \rightarrow 2Na^+ + 2OH^– + H_2↑$
  • The reactivity of group 1 metals increases with increasing atomic radius and lowering of ionization enthalpy down the group.
  • Thus, sodium having lower ionization enthalpy, is more reactive than lithium.
  • Hence, lithium reacts slowly while sodium reacts vigorously with water.
  • Since the reaction of sodium with water is highly exothermic, it catches fire when put in water.

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