- ✓${1^o},\,{2^o}$ and ${3^o}$ alcohols
- B${1^o},\,\,{2^o}$ and ${3^o}$ amines
- CAldehydes and ketones
- DAlkenes and alkynes
Lucas reagent is a solution of anhydrous zinc chloride in concentrated hydrochloric acid.
The Lucas test in alcohols is a test to differentiate between primary $\left(1^{\circ}\right)$, secondary $\left(2^{\circ}\right)$, and tertiary $\left(3^{\circ}\right)$ alcohols.
Tertiary alcohols react immediately with Lucas reagent.
Secondary alcohols react within $10-15$ minutes (depending on their solubility).
Primary alcohols do not react appreciably with Lucas reagent at room temperature.
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$MgO(s) + C(s) \to Mg(s) + CO(g)$, for which $\Delta _r{H^o} = + 491.1\,kJ\,mo{l^{ - 1}}$ and $\Delta _r{S^o} = 198.0\,Jk^{-1}\,mo{l^{ - 1}}$ is not feasible at $298\, K$. Temperature above which reaction will be feasible is.....$K$
$\left[\right.$ Given : $pK _{ b }\left( NH _3\right)=4.745$
$\log 2=0.301$
$\log 3=0.477$
$T =298\,K ]$