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Assertion $A$ : $\left[ CoCl \left( NH _3\right)_5\right]^{2+}$ absorbs at lower wavelength of light with respect to $\left[ Co \left( NH _3\right)_5\left( H _2 O \right)\right]^{3+}$
Reason $R$ : It is because the wavelength of the light absorbed depends on the oxidation state of the metal ion.
In the light of the above statements, choose the correct answer from the options given below :
$A, \,C$ and $D$ are
$C{H_3}C{H_2}C{H_2}Br\xrightarrow{{KOH(alc)}}(A)\xrightarrow{{HBr}}(B)\xrightarrow{{KOH\,(aq.)}}(C),$
${O_3}(g)\, + \,C{l^ * }(g)\, \to \,{O_2}(g) + Cl{O^ * }(g)$ ..... $(i)$ $[{K_i} = 5.2 \times {10^9}\,\,L\,mo{l^{ - 1}}\,{s^{ - 1}}]$
$Cl{O^ * }(g) + {O^ * }(g)\, \to \,{O_2}(g) + \,C{l^ * }(g)$ ..... $(ii)$ $[{K_{ii}} = 2.6 \times {10^{10}}\,\,L\,mo{l^{ - 1}}\,{s^{ - 1}}]$
The closest rate constant for the overall reaction
${O_3}(g){\mkern 1mu} + {\mkern 1mu} {O^*}(g){\mkern 1mu} \to {\mkern 1mu} 2{O_2}(g)$ is ........... $L\,\,mo{l^{ - 1}}\,{s^{ - 1}}$