
- A$A-(III), (B)-(IV), (C)-(I), (D)-(II)$
- ✓$A-(IV), (B)-(II), (C)-(I), (D)-(III)$
- C$A-(IV), (B)-(II), (C)-(III), (D)-(I)$
- D$A-(III), (B)-(IV), (C)-(II), (D)-(I)$

$\mathrm{C}_6 \mathrm{H}_5 \mathrm{COC}_6 \mathrm{H}_5 \xrightarrow{\mathrm{Zn}(\mathrm{Hg}) \& \text { conc. } \mathrm{HCl}} \mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{C}_6 \mathrm{H}_5$
$\mathrm{C}_0 \mathrm{H}_5 \mathrm{CHO} \xrightarrow[\mathrm{H}, \mathrm{O}]{\mathrm{CH}_3, \mathrm{Mgr}} \mathrm{C}_0 \mathrm{H}_5 \mathrm{CH}(\mathrm{OH}) \mathrm{CH}_5$
$\mathrm{CH}_3 \mathrm{COCH}_2 \mathrm{COOC}_2 \mathrm{H}_5 \xrightarrow{\text { Nath }, \mathrm{H}^{+}} \mathrm{CH}_3 \mathrm{CH}(\mathrm{OH}) \mathrm{CH}_2 \mathrm{COOC}_2 \mathrm{H}_5$
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$Pt$ $\mid H _{2}$ $(g,1 \,bar)$ $\left| H ^{+}( aq ) \| Cu ^{2+}( aq )\right| Cu ( s )$
is $0.31\, V$. The $pH$ of the acidic solution is found to be $3 ,$ whereas the concentration of $Cu ^{2+}$ is $10^{- x } \,M$. The value of $x$ is $.....$
(Given: $E _{ Cu ^{2+} / Cu }^{\ominus}=0.34 \,V$ and $\frac{2.303 RT }{ F }=0.06\, V$ )