Arrange the hydrogens $a, b, c, d$ in decreasing order of their reactivities towards chlorination
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$S{O_2}C{l_2}\left( g \right) \rightleftharpoons S{O_2}\left( g \right) + C{l_2}\left( g \right)$
$CO\left( g \right) + C{l_2}\left( g \right) \rightleftharpoons COC{l_2}\left( g \right)$
on adding more $SO_2$ at equilibrium what will happen?
${H_2}C = CH - CH = C{H_2}\xrightarrow[{0{\,^o}C}]{{HBr}}$ $\begin{array}{*{20}{c}}
{{H_2}C = CH - CH - C{H_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,Br\,\,\,\,\,\,}
\end{array}\xrightarrow{{ + 25{\,^o}C}}$ $\begin{array}{*{20}{c}}
{C{H_2}CH = CHC{H_3}} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{Br\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
These provide an example of $......1......$ control at low temperature and $......2......$ control at higher temperature
