MCQ
Migratory aptitude of the following in decreasing order is


- A$a > c > b > d$
- ✓$a > d > b > c$
- C$a > d > c > b$
- D$b > c > a > b$


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$(I) \,C{H_3}CH = C{H_2} + HBr\xrightarrow{{peroxide}}$
$(II)\, C{H_3}CH = C{H_2} + HBr\xrightarrow{{CC{l_4}}}$
$(III)\, C{H_3}C{H_2}C{H_3} + B{r_2}\xrightarrow{{hv}}$
$(IV)\,C{H_3}CH = C{H_2} + B{r_2}\xrightarrow{{CC{l_4}}}$
In an experiment, $2.0$ $moles$ of $NOCl$ was placed in a one-litre flask and the concentration of NO after equilibrium established, was found to be $0.4$ $mol / L$. The equilibrium constant at $30^{\circ} C$ is $.......\times 10^{-4}$