p -Block elements - ll — Chemistry STD 12 Science — Question

$ 3 \mathrm{ROH}+\mathrm{PCl}_3 \rightarrow 3 \mathrm{RCl}+\mathrm{A} $

$ \mathrm{ROH}+\mathrm{PCl}_5 \rightarrow \mathrm{RCl}+\mathrm{HCl}+\mathrm{B}$

$(At. No. Ti = 22, V = 23, Cr = 24, Mn=25)$

$2NO_2(g) + O_3(g) \to N_2O_5(g) + O_2(g)$

rate law is $R = K\, [NO_2]' [O_3]'$.

Which of these possible reaction mechanisms is consistent with the rate law?

Mechanism $I :$

$NO_2(g) + O_3(g) \to NO_3(g) + O_2(g)$ (slow)

$NO_3(g) + NO_2(g) \to N_2O_5(g)$ (fast)

Mechanism $II :$

$O_3(g)  \rightleftharpoons  O_2(g) + [O]$ (fast)

$NO_2(g) + [O] \to NO_3$ (slow)

$NO_3(g) + NO_2(g) \to  N_2O_5$ (fast)