On complete hydrolysis of starch, we finally get
AIPMT 1991, Easy
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R\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\, \\
{{H}_{2}}N-CH-COOH \\
\end{matrix}$ If $R = -CH_2C_6H_5$ then it is phenylalanine $(Phe)$ and if $R = CH_3$ then it is alanine $(Ala)$. Find the sequence of reagents from those given below to synthesize $Phe- Ala$$(1)$ $\begin{matrix}
C{{H}_{3}} \\
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\end{matrix}$ $(2)$ $\begin{matrix}
C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
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\end{matrix}$$(3)$ $\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}}{{C}_{6}}{{H}_{5}} \\
|\,\,\,\,\, \\
ZNH\,C\,HC{{O}_{2}}H \\
\end{matrix}$ $(4)$ $\begin{matrix}
C{{H}_{2}}{{C}_{6}}{{H}_{5}}\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
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\end{matrix}$