- ✓deactivates the ring towards electrophilic substitution
- Bactivates the ring towards electrophilic substitution
- Crenders the ring basic
- Ddeactivates the ring towards nucleophilic substitution.
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(Note: Degree of dissociation ( $\alpha$ ) of weak acid and weak base is $<<1$; degree of hydrolysis of salt $<<1 ;\left[ H ^{+}\right]$represents the concentration of $H ^{+}$ions)
| $LIST-I$ | $LIST-II$ |
|
$P$ $(10 mL $of $0.1 M NaOH +20 mL$ $of 0.1 M $ acetic acid) diluted to $60 mL$ |
$1$ the value of $\left[ H ^{+}\right]$does not change on dilution |
|
$Q $ $(20 mL $ of $ 0.1 M NaOH +20 mL $of $0.1 M $ acetic acid) diluted to $ 80 mL$ |
$2$ the value of $\left[ H ^{+}\right]$changes to half of its initial value on dilution the value of $\left[ H ^{+}\right]$changes to two times of its initial value on dilution |
|
$R$ $(20 mL $ of $ 0.1 M HCl +20 mL$of $0.1 M$ ammonia solution) diluted to $80 mL$ |
$3$ the value of $\left[ H ^{+}\right]$changes to $1 / \sqrt{2}$ times of its initial value on dilution |
|
$S$ $10 mL$ saturated solution of Ni $( OH )_2$in equilibrium with excess solid Ni $( OH )_2$ s diluted to $20 mL$ (solid Ni $( OH )_2$ is still present afterdilution). |
$4$the value of $\left[ H ^{+}\right]$changes to $\sqrt{2}$ times of its initial value on dilution |
| $5$ the value of $\left[ H ^{+}\right]$changes to $\sqrt{2}$ times of its initial value on dilution |
Match each process given in $LIST-I$ with one or more effect(s) in $LIST-II$. The correct option is
( electron charge $= 1.60\times10^{-19}\, C$)
(Given, $\frac{ d (\ln K )}{ d \left(\frac{1}{T}\right)}=-\frac{\Delta H^{\ominus}}{ R }$, where the equilibrium constant, $K =\frac{ p _{ z }}{ p ^{\ominus}}$ and the gas constant, $R =8.314$ $\left.J K ^{-1} mol ^{-1}\right)$
($1$) The value of standard enthalpy, $\Delta H ^{\ominus}$ (in $kJ mol ^{-1}$ ) for the reaction is. . . . . . .
($2$) The value of $\Delta S^{\ominus}$ (in $J K ^{-1} mol ^{-1}$ ) for the given reaction, at $1000 K$ is. . . . . .
Give the answer or quetin ($1$) and ($2$)