- ✓Negligible screening effect of $'4f'$ orbitals
- BNegligible screening effect of $'5f'$ orbital
- CDecreasing nuclear charge
- DIncreasing screening effect
Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.
${O_3}(g)\, + \,C{l^ * }(g)\, \to \,{O_2}(g) + Cl{O^ * }(g)$ ..... $(i)$ $[{K_i} = 5.2 \times {10^9}\,\,L\,mo{l^{ - 1}}\,{s^{ - 1}}]$
$Cl{O^ * }(g) + {O^ * }(g)\, \to \,{O_2}(g) + \,C{l^ * }(g)$ ..... $(ii)$ $[{K_{ii}} = 2.6 \times {10^{10}}\,\,L\,mo{l^{ - 1}}\,{s^{ - 1}}]$
The closest rate constant for the overall reaction
${O_3}(g){\mkern 1mu} + {\mkern 1mu} {O^*}(g){\mkern 1mu} \to {\mkern 1mu} 2{O_2}(g)$ is ........... $L\,\,mo{l^{ - 1}}\,{s^{ - 1}}$
Statement $I$ : Picric acid is $2, 4, 6$-trinitrotoluene.
Statement $II$ : Phenol$-2, 4-$disulphuric acid is treated with conc. $\mathrm{HNO}_3$ to get picric acid.
In the light of the above statement, choose the most appropriate answer from the options given below :
| Exp. | $[A]$ | $[B]$ | Rate of reaction |
| $1$ | $0.1$ | $0.1$ | $2 \times {10^{ - 3}}\,mol\,{L^{ - 1}}\,{\sec ^{ - 1}}$ |
| $2$ | $0.4$ | $0.1$ | $0.4 \times {10^{ - 2}}\,mol\,{L^{ - 1}}\,{\sec ^{ - 1}}$ |
| $3$ | $0.1$ | $0.2$ | $1.4 \times {10^{ - 2}}\,mol\,{L^{ - 1}}\,{\sec ^{ - 1}}$ |
