MCQ
Saponification (basic hydrolysis) of  $\begin{matrix}
   {{C}_{6}}{{H}_{5}}\,COC{{H}_{3}}  \\
   ||\,\,  \\
   O\,\,  \\
\end{matrix}$ will yield [$O =$ mass $- 18$ isotope of oxygen]
  • A
    $\begin{matrix}
       O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
       ||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
       {{C}_{6}}{{H}_{5}}-C-{{{\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle-}$}}{O}}}^{-}}+H\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle-}$}}{O}\,C{{H}_{3}}  \\
    \end{matrix}$
  • $\begin{matrix}
       O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
       ||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
       {{C}_{6}}{{H}_{5}}-C-{{O}^{-}}+H\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle-}$}}{O}\,C{{H}_{3}}  \\
    \end{matrix}$
  • C
    $\begin{matrix}
       {{C}_{6}}{{H}_{5}}C{{O}^{-}}+H{{{\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle-}$}}{O}}}^{-}}  \\
       ||\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
       O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
    \end{matrix}$
  • D
    $\begin{matrix}
       {{C}_{6}}{{H}_{5}}C{{O}^{-}}+HOC{{H}_{3}}  \\
       ||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
       \underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle-}$}}{O}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \,\,\, \\
    \end{matrix}$

Answer

Correct option: B.
$\begin{matrix}
   O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   ||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   {{C}_{6}}{{H}_{5}}-C-{{O}^{-}}+H\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle-}$}}{O}\,C{{H}_{3}}  \\
\end{matrix}$
b

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