
- AIt has no geometrical isomer
- BIt is optically inactive because square planar complex have plane of symmetry
- CIt is optically active because it has symmetric carbon
- ✓It is optically active because it does not have plane of symmetry

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| Element | $IE_1$ | $IE_2$ | $IE_3$ | $IE_4$ |
| $W$ | $10.5$ | $15.5$ | $24.9$ | $79.8$ |
| $X$ | $8$ | $14.8$ | $78.9$ | $105.8$ |
Other two elements $Y$ and $Z$ have outer electronic configuration $ns^2$ $np^4$ and $ns^2$ $np^5$ respectively. According to given information which of the following compound $(s)$ is/are not possible
$(a)\, W_2Y_3\, (b)\, X_2Y_3\, (c)\, WZ_2\, (d)\, XZ_2$
In the above first order reaction the concentration of $\mathrm{PCl}_{5}$ reduces from initial concentration $50\, mol\,\mathrm{L}^{-1}$ to $10\, \mathrm{~mol} \,\mathrm{~L}^{-1}$ in $120\, minutes$ at $300\, \mathrm{~K}$. The rate constant for the reaction at $300\, \mathrm{~K}$ is $\mathrm{X}$ $\times 10^{-2} \mathrm{~min}^{-1}$. The value of $x$ is $......$
$[$ Given $\log 5=0.6989]$