
- A$(P)$ and $(Q)$ are same
- ✓$(P)$ and $(Q)$ are positional isomers
- CFormation of $(Q)$ involves hydride migration
- DFormation of $(P)$ is electrophilic addition

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$3 HC \equiv CH _{( g )} \rightleftharpoons C _{6} H _{6(\ell)}$
[Given: $\Delta_{f} G ^{\circ}( HC \equiv CH )=-2.04 \times 10^{5}\, J mol ^{-1}$
$\Delta_{f} G ^{\circ}\left( C _{6} H _{6}\right)=-1.24 \times 10^{5}\, J mol ^{-1} ; R =8.314\,\left. J K ^{-1} mol ^{-1}\right]$
(Consider heat capacity of all solutions as $4.2 J g ^{-1} K ^{-1}$ and density of all solutions as $1.0 \ g mL ^{-1}$ )
$1.$ Enthalpy of dissociation (in $kJ mol ^{-1}$ ) of acetic acid obtained from the Expt. $2$ is
$(A)$ $1.0$ $(B)$ $10.0$ $(C)$ $24.5$ $(D)$ $51.4$
$2.$ The $pH$ of the solution after Expt. $2$ is
$(A)$ $2.8$ $(B)$ $4.7$ $(C)$ $5.0$ $(D)$ $7.0$
Give the answer question $1$ and $2.$