MCQ
SN1 reaction is favoured by:
- ANon-polar solvents
- BBulky group on the carbon atom attached to the halogen atom.
- CSmall groups on the carbon atom attached to halogen atom.
- DAll the above
Explanation:
SN1 mechanism proceeds through carbocation formation and as stability of carbocation increases, it favours SN1 mechanism.
And as we add bulky group to carbon attached with halogen, carbocation formed will become more stable due to +I effect of bulky alkyl group so it favours SN1 mechanism.
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$Pt$ $\mid H _{2}$ $(g,1 \,bar)$ $\left| H ^{+}( aq ) \| Cu ^{2+}( aq )\right| Cu ( s )$
is $0.31\, V$. The $pH$ of the acidic solution is found to be $3 ,$ whereas the concentration of $Cu ^{2+}$ is $10^{- x } \,M$. The value of $x$ is $.....$
(Given: $E _{ Cu ^{2+} / Cu }^{\ominus}=0.34 \,V$ and $\frac{2.303 RT }{ F }=0.06\, V$ )