MCQ
Structures of alanine at $pH = 2$ and  $pH = 10$ are respectively
  • $\begin{array}{*{20}{c}}
    {C{H_3}\,\,\,\,\,}\\
    {|\,\,\,\,\,\,\,\,}\\
    {\mathop N\limits^ +  {H_3} - CH - COOH}
    \end{array}$ and $\begin{array}{*{20}{c}}
    {C{H_3}\,\,\,}\\
    {|\,\,\,\,\,\,\,}\\
    {{H_2}N - CH - CO{O^ - }}
    \end{array}$
  • B
    $\begin{array}{*{20}{c}}
    {C{H_3}\,\,\,}\\
    {|\,\,\,\,\,\,\,}\\
    {{H_2}N - CH - CO{O^ - }}
    \end{array}$ and $\begin{array}{*{20}{c}}
    {C{H_3}\,\,\,\,\,}\\
    {|\,\,\,\,\,\,\,\,}\\
    {\mathop N\limits^ +  {H_3} - CH - COOH}
    \end{array}$
  • C
    $\begin{array}{*{20}{c}}
    {C{H_3}\,\,\,}\\
    {|\,\,\,\,\,\,\,}\\
    {{H_2}N - CH - CO{O^ - }}
    \end{array}$ both
  • D
    $\begin{array}{*{20}{c}}
    {C{H_3}\,\,\,\,\,}\\
    {|\,\,\,\,\,\,\,\,}\\
    {\mathop N\limits^ +  {H_3} - CH - COOH}
    \end{array}$ both

Answer

Correct option: A.
$\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,}\\
{\mathop N\limits^ +  {H_3} - CH - COOH}
\end{array}$ and $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,}\\
{|\,\,\,\,\,\,\,}\\
{{H_2}N - CH - CO{O^ - }}
\end{array}$
a
Alanine zwitter ion is $\begin{array}{*{20}{c}}
  {C{H_3}\,\,} \\ 
  {|\,\,\,\,\,\,\,\,} \\ 
  {{H_3}\mathop N\limits^ \oplus   - CH - CO{O^\Theta }} 
\end{array}$

$\begin{array}{*{20}{c}}
  {{H_3}\mathop N\limits^ \oplus   - CH - COOH} \\ 
  {|\,\,\,\,\,\,\,\,\,\,} \\ 
  {C{H_3}\,\,} 
\end{array}$  $\underset{{O{H^\Theta }}}{\overset{{{H^ \oplus }}}{\longleftrightarrow}}$ $\begin{array}{*{20}{c}}
  {{H_3}\mathop {\mathop N\limits^ \oplus   - CH - CO{O^\Theta }}\limits^{} } \\ 
  {|{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} } \\ 
  {C{H_3}} 
\end{array}$ $\underset{{^\Theta OH}}{\overset{{{H^ \oplus }}}{\longleftrightarrow}}$  $\begin{array}{*{20}{c}}
  {{H_2}N - CH - CO{O^\Theta }} \\ 
  {|\,\,\,\,\,\,\,\,} \\ 
  {\,C{H_3}\,\,} 
\end{array}$

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