MCQ
$\text{H}-\text{C}\equiv\text{C}-\text{H}\xrightarrow[(\text{ii})\ \text{CH}_3\text{CH}_2\text{Br}]{(\text{i})\ \text{NaNH}_2/\text{liq NH}_3}\text{X}\xrightarrow[(\text{ii})\ \text{CH}_3\text{CH}_2\text{Br}]{(\text{i})\ \text{NaNH}_2/\text{liq NH}_3}\text{Y}$
  • A
    $X$ is $2-$ butyne $Y$ is $2$ hexyne.
  • B
    $X$ is $1-$ butyne, $Y$ is $2-$ hexyne.
  • $X$ is $1-$ butyne $Y$ is $3-$ hexyne.
  • D
    $X$ is $2-$ butyne, $Y$ is $3-$ hexyne.

Answer

Correct option: C.
$X$ is $1-$ butyne $Y$ is $3-$ hexyne.
$\text{HC}\equiv\text{C}-\text{CH}_2-\text{CH}_3+\text{NaNH}_2\xrightarrow{\text{liq NH}_3}\text{NaC}\equiv\text{C}-\text{CH}_2\text{CH}_3$
$+\text{CH}_3-\text{CH}_2-\text{Br}\rightarrow\text{CH}_3-\text{CH}_2-\text{C}\equiv\text{C}-\text{CH}_2-\text{CH}_3$

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